AQUASTECH

Innovative technologies for advanced removal of inorganic and organic micropollutants such as arsenic and byproducts of chlorine disinfection (trihalomethanes and haloacetic acids) in the implementation context of new European legislation of drinking water quality – AQUASTECH

Team Leader:  Dr. Chim. Mihai ȘTEFĂNESCU

Short description: The aim of the project is to develop two experimental models/technologies, validated on laboratory level, for drinking water treatment from groundwater and surface sources.

These goals were established taking into account the specific of water sources on national level (specific objective 1 – technology for groundwater sources with arsenic content especially) and the situation of drinking water treatment technologies in Romanian water treatment plants and at international level (specific objective 2 – applicable technology in all cases where chlorine disinfection is used and there is a high potential of THMs and HAAs generation.

These technologies which will be developed in this project are as following:

  • Experimental model A: Optimized filtration technology for advanced removal of arsenic and heavy metals using alternative filtration support materials;
  • Experimental model B: Technology for removal of chlorine disifection byproducts (trihalomethanes – THMs, haloacetic acids
  • HAAs) by ultrasonication and reduction/dehalogenation with zerovalent iron (ZVI).

Technologies will be created gradual following the below mentioned research steps:

  • the study of physical-chemical behavior of target micropollutants (arsenic III, V, trihalomethanes, haloacetic acids) in aqueous system and the present technological level regarding the possibilities of their removal from raw waters (As) and inadequate treated (THMs, HAAs);
  • preliminary tests performing for each type of pollutant in order to find the operational parameters and determinant factors for their removing from synthetic aqueous solutions;
  • experiments performing in order to establish optimal and type of operating system;
  • performing of demonstrative tests of functionality for both proposed experimental models;
  • validation of these two experimental models/technologies for water potabilization.

It will be considered the developing of novelty and innovation aspects (for each experimental model) in two directions: using of new filtering support materials for the treatment step of filtration/sorption of raw water from underground source, as a component of classic potabilization technology in water treatment plants and creatin of a new technology, on national level, for advanced removal of chlorine disinfection byproducts from drinking water.

The impact of the project results will be in the realm of theoretical and practical research but in economic and social domain taking inti account the water is indispensable to life and a resource for industry and agriculture and must be efficient used in the context of social and economical changes in the future.

Phase 1/2023:

Studies and preliminary research of the proposed technological concepts:

  • Study regarding the groundwater quality of West Area of Romania
  • Study regarding the removal methods of THMs and HAAs from drinking water

Phase 2/2023:

Elaboration of experimental models:

  • Experimental study of advanced arsenic removal from drinking water by precipitation-coagulation and filtration through specific supports materials
  • Experimental study of trihalomethanes removal from water by zerovalent iron reduction and direct ultrasonication methods

Phase 3/2024

  • Technical and scientific report on the advanced removal of arsenic from selected groundwater sources from the aquifer of the Western Zone of Romania through laboratory-level testing of new filter materials for drinking water treatment
  • Technical and scientifical report of trihalomethanes and haloacetic acids from water using heterogeneoussystems with zerovalent iron and ultrasonicanion with zerovalent iron (US+ZVI)

Phase 3/II/2024

  • Technical and scientific report (Experimental study) on the study of identification and quantification of arsenic speciation present in selected groundwater sources (from the Western Rural Area of Timiș County) and testing of the experimental model on arsenic removal (As (III), As (V)) by aeration, pre-oxidation, coagulation-flocculation, sedimentation and rapid filtration on sand and natural zeolite;
  • Techical and scientifical report (experimental study) for experimental model testing of haloacetic acids removal from water by Fenton UV photolysis

Phase 4/2024

  • Technical and scientific report (experimental model) on the establishment of specific parameters for aeration, pre-oxidation, coagulation-flocculation and sedimentation processes as technological phases to the technologies resulting from the testing of experimental models applied for the advanced removal of arsenic
  • Technical and scientifical report (experimental model) of developing study of the resulted  technological phases from experimental models testing for haloacetic acids and trihalomethanes removal from water.

II. Papers presented at scientific events

  1. Pacala Adina, Stefanescu Mihai, Neidoni Dorian Gabriel, Diaconu Lidia Ani, Iordache Iuliana Elena, Piciorus Elena Mirela, Negrea Sorina Claudia Assessment of groundwater resources quality in the Western region of Romania 26th International Symposium “The Environment and the Industry”, SIMI 2023, September, 28-29, 2023, Bucuresti, Romania 2023;
  2. Pacala Adina, Stefanescu Mihai, Vasile Gabriela-Geanina Groundwater quality monitoring study in the West region of Romania 29th International Symposium on Analytical and Environmental Problems, Szeged, Hungary, November, 13-14 PROCEEDINGS OF THE 29thInternational Symposium on Analytical and Environmental Problems, ISBN 978-963-306-963-9, pp. 254-257 2023